110073: Synthesis and Processing of Cubic LiLaZrO for Use in Lithium Ion Batteries and Fuel Cells
Case ID:
TEC2011-0073
Web Published:
7/21/2014
Description:
Lithium
ion batteries are used in a wide variety of consumer goods such as cell phones,
mp3 players, and digital cameras. These products are becoming increasingly
smaller, requiring a smaller battery. Although lithium-based batteries provide
superior energy densities over other battery types, lithium is high reactive
with water. To safeguard against fire and thermal runaway, lithium batteries are
currently encapsulated in packaging containing vents and thermal interrupts,
which are space consuming. Eliminating the need for packaging reduces battery
size and cost.
Description
Michigan
State University’s invention involves a new method of synthesizing cubic lithium
lanthanum zirconium oxide (LiLaZrO or LLZO) powders and consolidating the
powders into a forms useful to solid state Li/Na ion batteries and Li/Na
seawater/air semi fuel cells. LLZO serves as the electrolyte, is not moisture
sensitive, and is stable when in contact with lithium. Integration of highly
ordered hierarchical cathode electrodes with the ceramic electrolyte improves
battery performance by reducing cathodic fowling. This new electrolyte improves
safety and performance.
The
invention includes a new procedure to construct the cathode, which maintains
mass transport of oxygen and reduces fowling at the cathode. It also includes a
new sol-gel method to synthesize the LiLaZrO electrolyte, which is easier and
more environmentally friendly, and a new procedure to construct the Li
anode/LiLaZrO electrolyte interface that lowers impedance.
Benefits
·
Stable in air
·
Increased power density
·
No need for exterior packaging making the battery
smaller
Applications
·
Primary battery applications, such as cameras, flashlights,
GPS units
·
Backup power
·
Military, such as radios, GPS units, and night vision
equipment
IP Protection
Status
Patent
pending
Patent Information:
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Serial No. |
Patent No. |
File Date |
Issued Date |
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For Information, Contact:
Bradley Shaw
Technology Manager
Michigan State University - Test
517-355-2186
shawbr@msu.edu